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Nitrate moleculeWhat are Nitrate and Nitrite?

Nitrate and nitrite are soluble compounds containing nitrogen and oxygen. In the environment, nitrite (NO2 - ) generally converts to nitrate (NO3 - ), which means nitrite occurs very rarely in groundwater. Nitrate is essential for plant growth and is present in all vegetables and grains. For this reason, the predominant use of nitrate in industry is for fertilizer. Nitrite is used for curing meats, manufacturing explosives, and for maintenance of industrial boilers. According to the World Health Organization, the average American male consumes 9-22 milligrams of nitrate-N per day primarily from leafy greens and root vegetables like carrots, beets, and radishes. Average nitrite-N consumption is much lower at 0.1-0.8 mg per day, primarily from cured meats. Intake at these levels is not considered a health risk.

Nitrate plus Nitrite Test Results

Testing labs generally analyze for nitrate and nitrite together so the results are often written as nitrate+nitrite as N (nitrate+nitrite-N). The drinking water standard for nitrite-N is 1.0 mg/L. However, nitrite is very uncommon in groundwater, so it is generally assumed that almost all of the nitrate plus nitrite is in the nitrate form. Natural levels of nitrate-N vary from zero to about 4 mg/L. If the value is above 4 it is possible that nitrate-N is moving into groundwater from a surface landuse or a septic system. Nitrate-N values exceeding 8 mg/L are approaching the health standard and should be monitored regularly especially if an infant under 1 year of age is using the water. Nitrate-N values over 10 mg/L are unsatisfactory and action should be taken to determine the source and discontinue use of the water for infants or people with cardiac problems.

What are the Health Risks?

The drinking water standard for nitrate-N is 10.0 mg/L, or 1 hundredth of a gram in one liter of water. The nitriteN standard is 1 mg/L. These standards only regulate public water supplies but are a relevant guide for private well owners.

Nitrate poses a particular threat to infantsThe major health risk from nitrate/nitrite is to infants under 6 months of age. At this early stage of development, nitrate in the body is transformed to nitrite, which reacts with hemoglobin (the oxygen carrier in the blood) and prevents transport of oxygen. The result is a decreased oxygen supply to the body, often called blue baby syndrome (or methemoglobinemia). It gets this name because the skin often turns a blue or grayish color, especially around the mouth. If these symptoms are noticed, seek medical attention immediately.

Adults are at low risk from this syndrome. Adults with chronic health problems, such as heart or lung disease or enzyme deficiencies, may be at higher risk from elevated nitrate/nitrite levels. Pregnant and nursing mothers should also avoid drinking water high in nitrate/nitrite because of potential effects passed on to the fetus or infant. There have been a few studies suggesting high nitrate/nitrite may cause certain types of cancer, but this connection is not well understood.

A septic system is a potential source of nitrateHow Does Nitrate get into Water Supplies?

Nitrate-N is found naturally in soil and water, but usually at relatively low concentrations (less than 4 mg/L in water). However, nitrate is highly soluble and is easily transported when contamination sources come into contact with water. Fertilizers are another potential source of nitrateCommon sources for nitrate contamination include septic systems, refuse dumps, fertilizers, manure, and decaying plant matter. Precipitation or irrigation will leach nitrate from these sources. As water percolates into the ground and runs over the surface, nitrate is carried into groundwater and/or surface water. Because nitrate is readily mobilized in water, it is often considered an early indicator that a pollution source is reaching a water supply.

What Steps can be Taken to Deal with High Nitrate Levels in Well Water?

  • After receiving results of high nitrate in your well water, retesting the water to confirm the value is recommended before investing in a new well or treatment system.
  • Bottled or treated water should be used for infants under 6 months of age.
  • Do not boil water to treat for nitrate; this will increase the concentration.
  • Steps should be taken to determine and remove the source of contamination. This could mean reduced fertilizer application, moving manure piles, pumping and maintaining septic systems, and ensuring that surface water does not flood the well head.
  • Drilling a deeper well into a non-contaminated aquifer.
  • Treatment systems available for nitrate removal include ion exchange, reverse osmosis, and electrodialysis. See the NSF website referenced below for more information.

Additional Resources

Water Quality Interpretation Tool:

http://region8water.colostate.edu/wqtool/index.cfm

Contact your County Sanitarian or Water Quality District.

World Health Organization Document (a comprehensive nitrate/nitrite document):

http://www.who.int/water_sanitation_health/dwq/chemicals/rrnitrates/en/

USEPA Safewater Page (General Nitrate/Nitrite information and drinking water standards):

http://www.epa.gov/safewater/contaminants/dw_contamfs/nitrates.html

NSF International Home Water Treatment Devices:

http://www.nsf.org/consumer/drinking_water/dw_treatment.asp?program=WaterTre